

Abstract: Although the synthesis of coloured corundum became widespread long ago, it may still be difficult to distinguish some natural and synthetic specimens especially if no inclusions are visible. The analysis of oxygen isotopic composition in combination with standard gemmological measurements (especially UV spectroscopy) can prove very useful in the identification of hydrothermal synthetic and flux synthetic corundums and in distinguishing them from natural stones. The indicator of flux synthesis is the presence of a 290 nm line in the photoluminescence spectrum and hydrothermal synthetic corundums contain negative δ18O values.
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